sodium phosphate in treated boiler water


1. External treatment: Treatment of water—makeup, condensate, or both, before it enters the boiler, to reduce or eliminate chemicals (such as hardness or silica), gases or solids. 2. Internal treatment: Treatment of the boiler feed water, boiler water, steam, or condensate with corrective chemicals. 3.

Boiler Water Treatment - ScienceDirect

However, the coordinated phosphate treatment is not efficient at high pressures (>160 bar) and temperatures due to the low solubility of sodium phosphate, resulting in phosphate hideout that results in pH excursion in the boiler water.

Water treatment of steam boilers - SlideShare

Aug 02, 2015 · To maintain a phosphate level of 60 ppm, the required sodium hexa meta phosphate is 4.36 lbs/day (Refer example 6) So total hexa meta phosphate required = 3.45 + 4.36 = 7.81 lbs/day Determination of Caustic Soda required The boiler water hydroxyl alkalinity should be maintained between 20 – 200 ppm to avoid corrosion and magnesium phosphate sludge formation.

The Role of Calcium Phosphate in Internal Boiler Water Treatment

This chapter is devoted to boiler water scale/deposit control in general, with a detailed description of various treatments based on phosphate chemistry. Depending on the boiler steam pressure, scale control is achieved by a combination of internal treatment and improvement in the quality of feed water to the boiler.

Boiler Water Treatment - Why is It Important

PH control is by the addition of chemicals like Tri-Sodium Phosphate in the boiler water or the “caustic treatment." This helps in maintaining the pH levels in the range of 9.0, slightly alkaline. The chemical reactions result in the formation of salts, which increases the dissolved solids level.

Steam Purity -

•SODIUM –The sodium in steam can come from the boiler water chemicals as sodium phosphate (phosphate chemistry program) or from the pH/alkalinity contributed by sodium hydroxide in the chemistry program or both.


Treatment in boilers (non congruent) LP tank blrs (<14 bar) Na 2 CO 3 – precipitates salts, provides alkalinity MgSO 4 – Sludge conditioners. Na 2 CO 3 can break down to form NaOH in higher rated boilers hence initial dose with Na 2 SO 4. Medium pressure tank blrs (<17.5 bar) Na 2 CO 3 (3) + sodium phosphate(4) + sludge conditioners(1)

Boiler water treatment - Lenntech

Boiler water treatment. These chemicals react with calcium and magnesium compounds in the feed water. Sodium silicate is used to react selectively with magnesium hardness. Calcium bicarbonate entering with the feed water is broken down at boiler temperatures or reacts with caustic soda to form calcium carbonate.

Phosphate Polymer Treatment for Steam Boilers

Accepta 2347 is a blended liquid treatment of polymers and is an ideal treatment for steam boilers using softened make-up water. Accepta 2347 is effective against iron and phosphate sludges. The organic polymer provides transport of the calcium, magnesium, iron, phosphate and silica through the boiler.

Will dosing a boiler with sodium phosphate affect the pH

Your original mixture with [math]Na_2HPO_4/Na_3PO_4[/math] will have a much higher pH than simply using [math]Na_2PO_4[/math] alone. The original solution will be

What Is a Boiler Feed Water Treatment System and How Does It

Sep 26, 2016 · Ion exchange softening. When pretreating boiler feed water, if there’s high hardness complexed with bicarbonates, sulphates, chlorides, or nitrates, a softening resin can be used. This procedure uses a strong acid cation exchange process, whereby resin is charged with a sodium ion, and as the hardness comes through,

Why do you inject phosphate in boiler feed water - Answers

Aug 10, 2010 · Alkaline sodium phosphate and pyrogallol (oxygen scavenger) was/is used for boiler water treatment and Silver nitrate was used to check for chloride presence. IAN M BARRETT Asked in Chemistry


tied up by dispersants and chelants and remain suspended in the boiler water where they can be removed by continuous surface or bottom blow down. Left improperly treated silica and iron both can form harmful deposits. ASME Phosphate Treatment Guidelines (boilers below 600 PSIG) OH-Alkalinity 100-600ppm Phosphate 30-50ppm Silica 200 - (0.25x

EP0640747A1 - Boiler system pH/phosphate program control

A pH/phosphate program in a boiler water system is controlled by: (1) determining the feed rate of the phosphate to the boiler by adding to a phosphate-feed stream containing the phosphate feeding to the boiler a phosphate-feed tracer in known proportion to the phosphate, determining the concentration of the phosphate-feed tracer in the phosphate-feed stream and correlating the phosphate-feed tracer concentration to the concentration of the phosphate; (2) determining the boiler cycles value

Boiler Water Treatment Chemicals, Feed, and Control – Perhaps

Sodium hexametaphosphate is a commonly used source of orthophosphate anion used to precipitate calcium in low pressure boilers. With dispersants the calcium phosphate becomes a fluidized sludge capable of being blown down and out of the boiler before the calcium can form

Boiler Water Treatment – PROWATER LTD

Boiler sludge concentrations created by coagulation treatment may be avoided by sodium phosphate treatment when water hardness is less than 60 mg/L. With adequate alkalinity, addition of sodium phosphate produces an insoluble precipitate of hydroxyapatite with magnesium hydroxide and magnesium and calcium silicates.

Using of congruent phosphate as equilibrium phosphate boilers

Equilibrium phosphate control is based on boilers water treatment by tri-sodium. phosphate for low pressure boilers and tri-sodium phosphate added low. concentration of sodium hydroxide for high pressure boilers as shown in fig.

Water Treatment -

Alkalinity. The tri-Sodium Phosphate based treatment is an alkaline product and in water initially decomposes to NaOH and Na2HPO4 but with increasing concentration will recombine. The di-Sodium Phosphate is much less alkaline. By the careful attention to pH and PO4 reserves correct treatment is managed by the addition

Program determines sodium-to-phosphate ratio in boiler water

This paper discusses sodium phosphate compounds, notably trisodium and disodium phosphate which have been used for years at many fossil-fired power plants for boiler water treatment. The principal purpose is to buffer the boiler water at a suitable pH while adding a compound, PO{sub 4}, which reacts with contaminants to form a non-adherent sludge.

Modelling of phosphate hideout in utility boilers (Technical

Phosphate based boiler water treatment programs continue to be widely utilized in utility power cycles. While this treatment scheme has a number of beneficial aspects, phosphate hide-out can be troublesome in some boilers. EPRI-sponsored laboratory testing of sodium phosphate boiler water treatment provided data on phosphate hide-out.

sodium phosphate – Water Technology Report

Apr 27, 2015 · Water Treatment Requirements for Low and Medium Pressure Boilers. Sodium sulfite Na2SO3 is the most commonly used and fastest acting oxygen scavenger. Available as a 90% active powder or less-concentrated liquid, sodium sulfite reacts rapidly with residual dissolved oxygen to form harmless sodium sulfate.

What Is a Boiler Feed Water Treatment System and How Does It

Sep 26, 2016 · What is a boiler feed water treatment system? A boiler feed water treatment system is a system made up of several individual technologies that address your specific boiler feed water treatment needs. Treating boiler feed water is essential for both high- and low-pressure boilers.

Sodium Hydroxide (25%) for pH Control, Boiler Feedwater

Accepta 1025 is a high quality concentrated sodium hydroxide (caustic soda) solution available at 25% for use in the treatment of boiler feedwaters. Accepta 1025 can also be used to regenerate anionic resins in deionisation plants.

sodium phosphate in treated boiler water

Boiler Water Treatment – PROWATER LTD. Boiler sludge concentrations created by coagulation treatment may be avoided by sodium phosphate treatment when water hardness is less than 60 mg/L. With adequate alkalinity, addition of sodium phosphate produces an insoluble precipitate of hydroxyapatite with magnesium hydroxide and magnesium and calcium silicates. Get a Quote

Sodium Nitrate in Steam Boilers — Heating Help: The Wall

I know youve never heard of anyone not checking their boiler water annually, i liken it to why do you change or check the oil in your car, when you dont believe in haveing your heating equipment checked annually, its about priorities i guess. anyway check archives from bell and gossett on the sodium phosphate advice..

The Effects of Carryover in Steam Boiler Systems

Aug 14, 2018 · If boiler water carryover is suspected, it can be verified by testing condensate for such parameters as sodium, phosphate, alkalinity, silica, or sulfite. If significant levels of these contaminants are detected, boiler water is being carried over into the steam.

High-Pressure Steam Cycle and Boiler Water Treatment

• New boiler water treatment was developed using the alkalinity derived from phosphate alone, eliminating sodium hydroxide – The sodium to phosphate ratio determines the pH of the water (3:1) – Ratio of trisodium to monosodium or disodium phosphate is adjusted to desired pH and phosphate levels can be attained without creating free

Boiler water chemistry - Properties of feed water explored

Let’s take a look at the boiler water chemistry and the effects resulting from the inability of maintaining the correct chemical equilibrium of the various properties. Properties and their effects. 1. pH. Controlling the PH of water is the first step towards boiler treatment.

Water Handbook - Preboiler & Industrial Boiler Corrosion

Sodium sulfite. 3 lb of sodium sulfite and 3 lb of caustic soda should be added per 1000 gal of water contained in the boiler (minimum 400 ppm P-alkalinity as CaCO3 and 200 ppm sulfite as SO3). Hydrazine. 5 lb of a 35% solution of hydrazine and 0.1 lb of ammonia or 2-3 lb of a 40% solution of neutralizing amine can be added per 1000 gal

Trisodium Phosphate - an overview | ScienceDirect Topics

With the development of higher temperature and pressure boilers, water treatment became more sophisticated. From 1857 to 1900 numerous patents described the use of tannins and other materials for treating boiler water. The use of disodium phosphate and trisodium phosphate came during this time period. Still, boiler explosions killed hundreds of

Why is phosphate dosing done in a boiler? - Quora

Tri – sodium phosphate solution is to be dosed in Boiler Drum / HRSG Drums to maintain water PH, to minimize potential acid and caustic corrosion in the drums. By dosing Tri sodium Phosphate (TSP), Boiler water PH shall be maintained slightly alkaline (9.00 – 9.2) and corrosion rate of ferrous alloys can be minimized.

Boiler Water Treatment in Marine Boilers - ShipFever

Similarly chemicals like that of sodium hydroxide, sodium carbonate, sodium hexa meta phosphate and Tri-sodium phosphate used to maintain alkalinity of the boiler water. Special corrosion inhibiting compound such as sodium bisulfite, carbohydrazide and cyclohexylamine are used to reduce scale formation in boiler tubes.

Boiler Water Treatment in Marine Boilers - ShipFever

Various set of chemicals are used for boiler water treatment. Oxygen scavenger such as hydrazine, carbohydrazide, sodium sulphate and tannin is used to remove the dissolved oxygen in the boiler water. This prevent boiler corrosion by removing or reducing oxygen content in the system.

5-2 Recovery Boiler Water Treatment

Phosphate (PO 4) 6Amount of Sodium Phosphate Dissolved in Boiler Water 6Units: ppm PO 4 = mg/L PO 4 6Purpose: ¾Stabilizes pH ¾Precipitates Hardness as Softer Deposits ¾Backup Indication of Hardness Contamination Phosphate/pH Control Curves 10.5 10.0 9.5 8.5 9.0 8.0 61014 18 22 26 30 p H Phosphate, mg/L 3.0 2.4 Na: PO M olar Ra 4 tio E q u il b r i u m L i n e ( 1 p

Water Chemicals | - Boiler Consortium

Sodium Hydroxide – NaOH or Caustic Soda, or Soda Ash – used to maintain boiler water pH in the 10.0 – 11.5 range. Hydroxide increase boiler alkalinity to prevent acidic corrosion. If heavy scale is present, caustic soda can accumulate to cause Caustic Attack. See pH Treatment.

Boiler Water Treatment | Sodium Chloride | Sodium Hydroxide

Phosphate Treatment Phosphate treatment is now universally used for all groups of boiler. Phosphate treatment is used in conjunction with either Sodium hydroxide, or Sodium carbonate How it works: Phosphate (as Trisodium phosphate) reacts with the scale forming salts to produce non-adhering sludge. Sodium hydroxide, increases the alkalinity of the water.

Section 3 - Module 10: Internal Water Treatment for Boilers

4. Sodium in the boiler water to form sodium carbonate that attacks the colder areas of the boiler water walls A) 1, 2 B) 2, 3 C) 3, 4 D) 1, 3 E) 1, 4

Understand the importance of water/steam chemistry

Like feed-water chemistry, boiler water chemistry has undergone a considerable evolution over the past two to three decades. For decades, phosphate programs have been the workhorse of many treatment programs. Tri-sodium phosphate provides alkalinity beyond that of ammonia. Na 3 PO 4 + H 2 O → NaOH + NaH 2 PO 4

Hot Water Boiler Chemical Guide - ChemWorld

Types of Boiler Chemicals for Hot Water Boilers By far the most popular hot water boiler chemical is a sodium nitrite blend. This chemical blend often contains a low percentage of borate, silicate, tolytriazole, and sodium hydroxide.

Boiler Water Chemicals | Steam Boiler Water Treatments

A complete water treatment programme for a steam boiler will usually include a chemical oxygen scavenger, alkalinity builder and polymer sludge conditioner and, depending on the application, may also incorporate a phosphate treatment and a condensate line treatment.