Dec 15, 2013 · Oxygen treatment for super critical power plants. OXYGEN TREATMENT FOR SUPER CRITICAL POWER PLANTS Supercritical boilers do not have a steam drum. Therefore, extremely high levels of purity is required for feed water Poor feed water can result into carry over of impurities which will result in turbine blade deposits Oxygen Treatment improves
The oxygen scavengers most commonly used in boiler systems are sodium sulfite, sodium bisulfite, hydrazine, catalyzed versions of the sulfites and hydrazine, and organic oxygen scavengers, such as hydroquinone and ascorbate.
Boiler Oxygen Scavengers. Oxygen related metallic corrosion is a significant issue in the operation and maintenance of industrial boiler systems and steam raising plant. To ensure that such boiler systems are well maintained and operate at optimum efficiency it is essential that the correct water conditions are maintained at all times.
All boiler tube and turbine blade failures influenced by cycle water chemistry have the breakdown of the passive protective layer as part of the failure mechanism. If you protect your protective layer 24/7 seven days a week 365 days a year, you will not have boiler or turbine blade failures due to cycle chemistry.
In some cases, the last rinse is treated with chemical to raise the pH to a normal boiler pH range, and the boiler is fired to 180F to 200F so that it can be drained hot and dried out.
A sulfite residual should be maintained in the boiler of about 5 to 20 mg/L as SO 3. The feed rate should be that shown in Table 3-5 plus 5 to 20 mg/L as sulfite divided by the boiler cycles.
Make-up water to steam boilers should be treated with oxygen scavengers to avoid serious corrosion problems. Fresh water contains dissolved oxygen. Oxygen together with high temperature is highly corrosive for the carbon steel piping used in steam systems. To avoid corrosion the oxygen in the make-up water for saturated steam production should be removed by using some kind of scavenger chemicals and/or deaeration towers.
Modern once-through supercritical units operates under an oxidizing treatment without the addition of an oxygen scavenger and in most cases with the addition of oxygen to the feedwater. During operation these units either operate with their deaerator vents closed or equipped with oxygen feeders at the deaerator outlets.
In the case of EDTA, passivation occurs after cooling the boiler to 160F and after the pH of the solvent is raised with ammonia (for diammonium EDTA) when oxygen is added. This also complexes any
oxygen conditions, similar to AVT, and to pH conditions of 8.5 to 9.0, lower than that of AVT. Thus, the iron concentration in the drain increased because the hematite-formation reaction was delayed due to low temperatures. Figure 5 Powdered scale deposited on the boiler generating tube |3. Countermeasures against Powdered Scale Deposition
dosage at 5 to 50 cycles only varies from 0.8% to 7.6% of the total required dosage. Changing the residual in the boiler if the deaerator is operating properly can change consumption significantly, but should have little impact on results, unless the deaerator dissolved oxygen level spikes above the 0.01 ppm level.
PT Conditioning regime for drum boilers in which alkalinity is achieved by dosing the boiler water with tri-sodium phosphate Stress Corrosion Cracking SCC A cracking mechanism that occurs in the steam turbine phase transition zone. Swallowing capacity Flow passing ability A measure of the volumetric capacity of the
The application of a fast-acting oxygen scavenger, such as catalyzed sodium sulfite, also helps protect this vital part of the boiler. While oxygen pitting is the most common form of waterside corrosion that causes economizer tube failures, caustic soda has occasionally accumulated under deposits and caused caustic gouging.
Yuhuan has China’s first 1,000MW ultra-supercritical pressure boilers. Units 1 and 2 went on line in 2006, and units 3 and 4 in 2007. The site is now generating 22 billion kWh of electricity a year. The plant is operated by China Huaneng Group, China’s largest power producer.
Oxygenated treatment (OT) is a technique used to reduce corrosion in a boiler and its associated feedwater system in flow-through boilers. With oxygenated treatment, oxygen is injected into the feedwater to keep the oxygen level between 30-50 ppb.
Jun 26, 2017 · The theoretical dosage of sodium sulfite (100% purity) is 8 ppm sulfite for every 1 ppm (0.7 cc per liter) of dissolved oxygen. However, correction must be made for the activity or purity of the commercial sulfite, which is about 90%, and for the efficiency of the scavenging reaction.
Mar 09, 2016 · 39 OXYGENATED TREATMENT OF FEED WATER Dosing of oxygen(O2) or Hydrogen peroxide (H2O2) in to feed water system. Concentration in the range of 50 to 300 µg/L. Formation of a thin, tightly adherent ferric oxide (FeOOH) hydrate layer. This layer is much more dense and tight than that of Magnetite layer.
The dissolved oxygen in the feedwater reacts with the metal scales of the boiler to form oxides. This can be prevented by using oxygen scavengers (also known as oxygen absorbers), that’ll remove or reduce the level of oxygen in the entire system.
3. Dissolved Oxygen in the feed water entering the boiler. 4. Silica in boiler water. Water Steam Circuit- Sub Critical vs Super Critcal Differences in a Supercritical Unit The Water Steam circuit in a Supercritical unit is different from that of a sub-critical unit. This makes the water quality requirement more stringent in a Supercritical unit.
Aug 13, 2009 · In modern boiler systems, dissolved oxygen is handled by first mechanically removing most of the dissolved oxygen and then chemically scavenging the remainder. The mechanical degasification is
May 05, 2015 · Boiler Chemistry Control and Treatment of Feed Water. In OT Ammonia is used to control pH and remove little Oxygen, but slightly oxidizing environment is maintained to promote formation of oxidizing layer on the metal surface. In supercritical plants as well as in subcritical plants with CPU, after start up Oxygen Treatment (OT) is done.
The standard recommended dosage level is 11 parts per 1 part of oxygen (as O 2). In addition, Erythorbic Acid is a vegetable-derived food preservative, and is a stereoisomer of ascorbic acid (Vitamin C).
4) eliminate oxygen from the water and provide enough alkalinity to prevent boiler corrosion. In addition, as supplementary measures an internal treatment should prevent corrosion and scaling of the feed-water system and protect against corrosion in the steam condensate systems.
The boiler feedwater is dosed with hydrazine as an oxygen scavenger. To monitor the effectiveness of the hydrazine dosing, a dissolved oxygen monitor is placed at the economiser inlet. This is to check that acceptable levels of dissolved oxygen have been removed (normally to below 5µgkg-1). A hydrazine monitor is also placed at the economiser inlet
Oxygen scavenger and passivator for steam raising plant, hydrazine replacement. Accepta 2512 is a high performance organic boiler water oxygen scavenger and passivator scientifically formulated for the treatment of steam raising plant. It can be used as a direct replacement for hydrazine, and contains 10% carbohydrazide.
However, in high-purity water systems, such as is used for supercritical boilers, the controlled addition of oxygen during operation is beneficial as it reduces corrosion product transport to the boiler and subsequently reduces the rate of deposition within the boiler.
Here are question and answer to Steam Power Plant and Power Generation Plants for steam boilers, turbine generator and heating problems. Dedicated to power plants, power generation, supercritical, and heating plants as well as steam boilers, steam turbine generators, gas turbines or combustion turbines, hrsg, steam heating, pressure vessels
Several important applications of the oxygen-enriched combustion in steam generators include the design of a new generation of advanced boilers and the gain in power resulting from the use of oxygen-enriched air in existing boilers. This paper tackles the first option, namely, the impact of oxygen enrichment on the boiler design.
Oxygen Scavengers to Prevent Corrosion: Corrosion of boilers occurs when untreated feedwater is used. The dissolved oxygen in the feedwater reacts with the metal scales of the boiler to form oxides. The dissolved oxygen in the feedwater reacts with the metal scales of the boiler to form oxides.
604 Appendix A: Supercritical Fossil Fired Power Plants – Design and Developments Typical Arrangement of a Benson Boiler Figure A.5  shows a typical arrangement of the latest large capacity supercritical
The presence of dissolved oxygen in boiler feedwater can present serious years sodium sulfite and hydrazine were the chemical oxygen scavengers of At high temperature iron corrodes in water to form magnetite as follows: In low to moderate pressure industrial boiler systems, an initial feedwater DEHA dosage.
B&W's supercritical and ultra-supercritical boilers are designed to take full advantage of variable pressure turbine operation. Specific advantages include: For a given output, lower fuel consumption, and thus lower carbon emissions, than other less efficient systems
Nov 09, 2017 · Oxygen is used in various points in a thermal power plant. But as I can understand from the question that you might be looking for why oxygen is directly injected inside the stream of water that converts into steam.
Boiler water quality is of prime concern to all boiler operators. The process of water treatment in boilers is not limited to producing high quality DM water. The stringent water chemistry requirements of Supercritical power plants makes water treatment in boilers a very critical aspect of power plant operation.
But recently, oxygen combustion in boilers has become one of the CCS technologies which can be an effective tool for reducing greenhouse gases emissions, and oxygen enriched combustion is suitable
A boiler's efficiency is directly related to the quality of its feedwater. The feedwater system refers to deaerator, feedwater pumps, and the piping to the boiler. Before water enters the boiler, oxygen must be removed or corrosion can occur throughout the boiler system, forming pits that eat away at the metal. Resulting leaks
A major cause of corrosion in boilers is dissolved oxygen, particularly in conjunction with low pH (low alkalinity) although excessive alkalinity can also be a factor. Chemical oxygen scavengers are used to eliminate oxygen from the feed water. The main types of oxygen scavenger are shown below:
Accepta 2512 is a high-performance organic boiler water oxygen scavenger and passivator scientifically formulated for the treatment of steam raising plant. It can be used as a direct replacement for hydrazine and contains 10% carbohydrazide. Accepta 2512 is suitable for use in boilers of any pressure up to and including supercritical (220 barg).
Hitachi, is one of the boiler manufacturers and environmental control system suppliers, had been developing new technologies for power plants including boiler, SCR, AQCS, amine-based scrubbing, oxy-fuel combustion, IGCC with CO2 absorption, and 700°C class advanced ultra supercritical boiler-turbine system, to tackle the issue of