silica in boiler water

Silica in steam - SlideShare

Aug 04, 2014 · SILICA SOLUBILITY Research on the solubility of silica in water and steam shows several important points: • Steam is a solvent for silica • For any particular steam density and temperature, there is a definite saturation solubility of silica Selective silica carryover Figure 1 — Silica distribution ratio Figure 2 — Maximum boiler water

Silica in boiler water | Emerald Insight

Steam contamination (solid particles in the superheated steam) comes from the boiler water largely in the carry‐over of water droplets. The need for extreme purity of steam for use in high pressure turbines has prompted the development of highly satisfactory devices for separating steam and water in a boiler drum.

Silica in steam - SlideShare

Aug 04, 2014 · The amount of silica expected in the steam from a particular boiler is shown by the intersection of the boiler pressure line and boiler water silica line. For example, a boiler operating at 1400 psi with 10 ppm silica in the boiler water would show about 0.04 ppm in the steam.

The Importance of Boiler Water and Steam Chemistry

Excessive steam impurity concentrations can also be caused by feedwater and boiler water chemistries that favor volatile species formation. Carryover of volatile silica can be problematic at pressures above 1000 psig (6.9 MPa). Vaporous silica carryover at a pH of 10.0 is 88% of that at a pH of 8.8.

Silica Scaling in Boilers - Lenntech

Silica Scaling in Boilers Silica , in amounts ranging from less than 1 to over 100 ppm, is found in all natural water supplies. In rain hail and snow, silica content range from 1 to 2.8 ppm.

What Is a Boiler Feed Water Treatment System and How Does It

Sep 26, 2016 · The most appropriate boiler feed water treatment system will help the facility avoid costly plant downtime , expensive maintenance fees, and boiler failure as a result of scaling, corrosion, and fouling of the boiler and downstream equipment.

Table 3-7. Silica Levels Allowed in Boiler Water

any water carryover is occurring is to measure the conductivity of the steam or of the. steam condensate. If you detect less than 25 micromhos conductivity in the condensate, then carryover is probably insignificant.

Boiler Water Treatment - Why is It Important

Boiler water quality is of prime concern to all boiler operators. The process of water treatment in boilers is not limited to producing high quality DM water. The stringent water chemistry requirements of Supercritical power plants makes water treatment in boilers a very critical aspect of power plant operation.

Critical HRSG | Power Engineering

Silica is a compound that will carry over vaporously into steam, which makes monitoring quite important in the boiler water and especially the steam.

Optimising power plant efficiency by measuring silica

If silica is not removed from the boiler feed water, it will concentrate itself on the drum and is carried over in steam to form adherent deposits in the steam passage way distorting the original shape of turbine nozzles and blades. This alters steam velocities and the pressure drops reducing the capacity and efficiency of the turbine.

The Effects of Silica on Steam Turbines | Sciencing

Carryover. Carryover is any contaminant that leaves the power station boiler within the steam that flows into the turbine. Silica is the most common contaminant. It volatilizes -- becomes a gas -- at the high pressures and temperatures within the boiler. It also forms a colloidal solution -- a stable suspension of silica particles -- with water.


• Small amount of boiler water drawn off near surface continuously or intermittently • Function is to control concentration of dissolved solids; provide correct boiler water chemistry • Bottom blowdown • Water emptied from mud drum or bottom of firetube boiler; function is removal of “sludge” • Done on regular schedule

Silica removal from water - Finishing

A. It is very possible that you have 10 mg/L of silica in your DI water. Silica is the first thing to leak off of an anion exchange resin and at pH values < 7 it is not ionized so it adds almost nothing to conductivity. If you want to have less silica in your DI water,

Boiler Feedwater Treatment (Part I): Why Water Treatment is

Silica can be present in the steam as the result of general boiler water carryover, or it can go into the steam in a volatile form. In the later case, silica acts much like gas and is considered to be selectively carried over.

Boiler water Limit:- - Altret

This value will limit the silica content of the steam to 0.25 ppm as a function of selective. Feed Water & Boiler water Characteristics as per IS:10392-1982 1.FEED WATER Parameters Upto 20 Kg/cm2 21 Kg/cm2 to 39 Kg/cm2 40 Kg/cm2 to 59 Kg/cm2 Unit Total Hardness <10 <1.0 <0.5 ppm as CaCO 3 pH Value 8.5-9.5 8.5-9.5 8.5-9.5 Dissolved Oxygen

Water Handbook -Boiler Deposits: Occurrence And Control | SUEZ

Sludge is the accumulation of solids that precipitate in the bulk boiler water or enter the boiler as suspended solids. Sludge deposits can be hard, dense, and tenacious. When exposed to high heat levels (e.g., when a boiler is drained hot), sludge deposits are often baked in place. Sludge deposits hardened in this way can be as troublesome as scale.


tied up by dispersants and chelants and remain suspended in the boiler water where they can be removed by continuous surface or bottom blow down. Left improperly treated silica and iron both can form harmful deposits. ASME Phosphate Treatment Guidelines (boilers below 600 PSIG) OH-Alkalinity 100-600ppm Phosphate 30-50ppm Silica 200 - (0.25x Boiler Pressure)

REMOVAL OF SILICA - Water Treatment of Silica

Water Treatment of Silica Natural waters, generally, contain about 5-8 mg/l of silica (Si0,). Another important source of silica in water is the sand When water treated by lime-soda process is filtered through a sand water filter, a good amount of silica dissolves in it (forming calcium and magnesium silicates) due to alkaline nature of waters.

(PDF) Concentration control of silica in water chemical

Two-stage acid cleaning (TSAC) operation has been employed and investigated to clean up undesired impurities (deposit) in boiler water wall tubes (BWWT), boiler drum, super heater, economizer

How many types of silica are present in boiler water? - Quora

Dec 20, 2018 · The non reactive silica converts to a reactive silica under the high temperature and pressure in the Boiler. Hence, it is preferred to remove the same from raw water by flocculation, wherein the non reactive silica gets adsorbed on the floc.

Boiler Water Treatment Basic - Boilersinfo

Boiler Water Treatment is necessary to Producing quality steam on demand depends on properly managed water treatment to control steam purity, deposits and corrosion.There are two main types of boiler feed water treatment Internal boiler Water Treatment method and external boiler water treatment. A boiler is the sump of the boiler system.

Steam Boiler: Silica Removal from Boiler Water

Silica removal from boiler water can be done by using dolomite lime or active magnesia in the softener. If using coagulation and previous deposition, some silica will can be removed by coagulate ferry. This substance is very suitable if concentration of silica is in additive water.

The Importance of Boiler Water and Steam Chemistry

An exception is silica for which vaporous carryover can be substantial at lower pressures. Vaporous carryover depends on pressure and on boiler water chemistry. It is not affected by boiler design. Hence, if vaporous carryover for a species is excessive, the carryover can only be reduced by altering the boiler water chemistry.

Steam Purity -

•Silica –normal saturated steam should be < 20 ppb in most boilers. High pH in the boiler water will reduce silica carryover from the boiler water. Monitor the steam because: •Precipitation of silica forms silicate deposits on the cold end of the turbine that are not water soluble and are very difficult to remove.

Steam and water analysis system - Wikipedia

Steam and water analysis system (SWAS) is a system dedicated to the analysis of steam or water. In power stations , it is usually used to analyze boiler steam and water to ensure the water used to generate electricity is clean from impurities which can cause corrosion to any metallic surface, such as in boiler and turbine.

Cycles of Concentration for Boilers - Taylor Industrial - Medium

Mar 07, 2017 · This can be verified in the field by testing for silica — dividing boiler water silica by feedwater silica. Example: A 50 psig boiler has a feedwater conductivity of 100 umhos and a silica level of 0.50 ppm. The boiler water “neutralized” conductivity is 3000 umhos and the silica level is 15 ppm.

How silica increases in boiler drum? - Quora

Answer Wiki. The deposition is mainly depends on the silica percentage in boiler feed water . water consists the silica which goes to steam drum in which steam and water separation takes place . The unwanted materials in water are settle at the bottom of the steam drum. Deposit in steam drum can remove by giving the blow down.

Boiler Water Quality

Silica in boiler feedwater can be a problem in larger steam boiler systems. You must maintain a Total OH alkalinity ratio of 3:1 in high pressure boilers to prevent plating of silica. Alkalinity is a measure of the capacity of water to neutralize strong acids.


water salts, such as silica and sodium compounds; or it may be caused by foam-ing. Carryover is most often a mechanical problem, and the chemicals found in the steam are those originally present in the boiler water, plus the volatile com-ponents that distill from the boiler even in the absence of spray.

Silica (SiO2) - Water Chemistry | Water Treatment | Water

Reactive silica is the form of silica to be used in RO projection programs. Reactive silica, though it has anionic characteristics, is not counted as an anion in terms of balancing a water analysis but it is counted as a part of total TDS. Unreactive silica is polymerized or colloidal silica, acting more like a solid than a dissolved ion.

Boiler Chemistry Control and Treatment of Feed Water

Silica from CW is another damaging factor as it deposits on turbine. Silica needs to be controlled at DM plant also. Silica needs to be controlled at DM plant also. The percentage of impurity allowed in boiler water/steam is function of boiler operating pressure, so, more critical for high pressure boilers.

silica in boiler water – lng-steam-boiler-manufacturer

Dec 22, 2017 · When this boiler water carryover silica in boiler water – Power generating facility 2003-9-24 · any clues as to how silica shows up in boiler water when demin supply is less than 2ppb and blow down is treated in an anion resin bed before re-entry to waterColloidal Silica – Treatment and RemovalIt is essential to remove colloidal silica from water to be used in high pressure boiler operations.


colloidal silica at high pressure and temperature gets converted into reactive silica due to which the silica level in the Boiler drum increases. In order to avoid scaling of silica on the turbine blades, lower level of total silica has to be maintained in the boiler drum and this calls for increase in blowdown from normal from 1% to 2%, due to which the boiler feed water capacity has to be increased from 20 m3/h to 40 m3/h. However, by installing a Ultrafiltration

Silica in boiler feed water - Metrohm

Silica in boiler feed water Excessive silica concentrations in the boiler feed water can lead to deposits on turbine blades and must therefore be avoided. Silica analysis is carried out via differential photometry using a leading-edge technology thermostatic cuvette module for non-sample contact at the detector.

An innovative, economical and efficient method of silica

Lime softening is one of the most common methods for removing silica from water such as make up to cooling towers, make up to boilers or boiler blow down water. Lime softening utilizes the addition of lime (calcium hydroxide) to remove hardness (calcium carbonate and magnesium carbonate) ions by precipitation.

Table 3-14. ASME Boiler Water Limits for Industrial Water

ASME Boiler Water Limits for Industrial Water Tube Boilers. ASME Boiler Water Limits for Industrial Water Tube ≤ 40 ≤ 30 ≤ 20 ≤8 ≤2 ≤1. Silica

Steam Boiler: Silica in Boiler Water

Silica in Boiler Water Silica is not soluble either in water or in acid and silica is usually in the form of colloids. Silica is found in almost all rocks and susceptible to weathering.

Silica in boiler feed water - Metrohm

Excessive silica concentrations in the boiler feed water can lead to deposits on turbine blades and must therefore be avoided. Silica analysis is carried out via differential photometry using a leading-edge technology thermostatic cuvette module for non-sample contact at the detector.

The Effects of Carryover in Steam Boiler Systems

Aug 14, 2018 · If boiler water carryover is suspected, it can be verified by testing condensate for such parameters as sodium, phosphate, alkalinity, silica, or sulfite. If significant levels of these contaminants are detected, boiler water is being carried over into the steam.

Silica Scaling in Boilers -

Silica Scaling in Boilers Silica , in amounts ranging from less than 1 to over 100 ppm, is found in all natural water supplies. In rain hail and snow, silica content range from 1 to 2.8 ppm.